새로운 광학활성을 갖는 Co:AlCl3 복합촉매를 이용한 terminal epoxides 의 HKR 반응에서의 높은 촉매활성에 대한 연구

초록

A wide variety of highly selective asymmetric reactions catalyzed by chiral (salen) metal complexes have been disclosed over the past decade. The solvent free hydrolytic kinetic resolution (HKR) of terminal epoxides catalyzed by a new chiral(salen) Co:AlCl3 complex is described. the catalyst show high reactivity and selectivity in good yields of > 98% ee under ambient condition within 1h.