Porous metal-organic frameworks derived carbon and nickel sulfides composite electrode for energy storage materials

  • Ramesh, Sivalingam
  • Yadav, H. M.
  • Afsar, N.
  • Haldorai, Yuvaraj
  • Shin, Kyeongho
  • ... Kim, Joo-Hyung
  • 외 2명
Citations

WEB OF SCIENCE

25
Citations

SCOPUS

25

초록

Researchers have extensively investigated the use of metal-organic frameworks (MOFs), which contain a greater surface area, high porosity, and controlled pore structure, in supercapacitors, sensors and biological applications. Here, we present a novel method for the sonication-improved hydrothermal reaction process of nickel sulfides decorated on metal organic framework derived carbon composite. The NiS@Ni-MOF composite has improved surface, morphological, and electrochemical properties after being annealed at an ideal temperature of 200 degrees C and then being subjected to a hydrothermal process. The composite electrode fabrication displays improved specific capacitances of 950 F/g at 1 A/g, long-lasting cycle stability, and exceptional capacitance retention in the presence of 6 M KOH electrolyte. Additionally, even at a high current density of 5 A g-1 and 5000 cycles, the capacitance retention can keep 99.7 % of its original value. The NiS@Ni-MOF composite's synergistic effects between its distinctive structural features are responsible for its superior electrochemical capabilities, which make it a promising electrode material for high performance supercapacitors.

키워드

Nickel sulfide (NiS)Metal organic frame work (MOF)CompositeSupercapacitorCyclic stabilityAnd excellent cyclic retentionHOLLOW SPHERESHIERARCHICAL STRUCTURESFACILE SYNTHESISTHIN-FILMSBETA-NISPERFORMANCESUPERCAPACITORNANOSTRUCTURESOXIDESNI3S4
제목
Porous metal-organic frameworks derived carbon and nickel sulfides composite electrode for energy storage materials
저자
Ramesh, SivalingamYadav, H. M.Afsar, N.Haldorai, YuvarajShin, KyeonghoLee, Young-JunKim, Joo-HyungKim, Heung Soo
DOI
10.1016/j.est.2023.109104
발행일
2023-12-15
유형
Article
저널명
Journal of Energy Storage
73