Porous metal-organic frameworks derived carbon and nickel sulfides composite electrode for energy storage materials

  • Ramesh, Sivalingam; 
  • Yadav, H. M.; 
  • Afsar, N.; 
  • Haldorai, Yuvaraj; 
  • Shin, Kyeongho; 
  • ... Kim, Joo-Hyung; 
  • 외 2명
Citations

WEB OF SCIENCE

27
Citations

SCOPUS

28

초록

Researchers have extensively investigated the use of metal-organic frameworks (MOFs), which contain a greater surface area, high porosity, and controlled pore structure, in supercapacitors, sensors and biological applications. Here, we present a novel method for the sonication-improved hydrothermal reaction process of nickel sulfides decorated on metal organic framework derived carbon composite. The NiS@Ni-MOF composite has improved surface, morphological, and electrochemical properties after being annealed at an ideal temperature of 200 degrees C and then being subjected to a hydrothermal process. The composite electrode fabrication displays improved specific capacitances of 950 F/g at 1 A/g, long-lasting cycle stability, and exceptional capacitance retention in the presence of 6 M KOH electrolyte. Additionally, even at a high current density of 5 A g-1 and 5000 cycles, the capacitance retention can keep 99.7 % of its original value. The NiS@Ni-MOF composite's synergistic effects between its distinctive structural features are responsible for its superior electrochemical capabilities, which make it a promising electrode material for high performance supercapacitors.

키워드

Nickel sulfide (NiS); Metal organic frame work (MOF); Composite; Supercapacitor; Cyclic stability; And excellent cyclic retention; HOLLOW SPHERES; HIERARCHICAL STRUCTURES; FACILE SYNTHESIS; THIN-FILMS; BETA-NIS; PERFORMANCE; SUPERCAPACITOR; NANOSTRUCTURES; OXIDES; NI3S4
제목
Porous metal-organic frameworks derived carbon and nickel sulfides composite electrode for energy storage materials
저자
Ramesh, Sivalingam; Yadav, H. M.; Afsar, N.; Haldorai, Yuvaraj; Shin, Kyeongho; Lee, Young-Jun; Kim, Joo-Hyung; Kim, Heung Soo
DOI
10.1016/j.est.2023.109104
발행일
2023-12-15
유형
Article
저널명
Journal of Energy Storage
권
73