Studies on the Synthesis and Characterization of Furoxan Derivatives

초록

The furoxan ring is a highly energetic heterocycle whose introduction into organic compounds is a known strategy for increasing crystal density and improving explosive performance. 3,4-Bis(nitrofurazano)furoxan (BNFF) has larger density, higher detonation velocity, and detonation pressure than HMX as a novel energetic material. The furoxan derivatives were prepared from commercially available malononitrile by multistep process, including dimerization of nitrile oxides and oxidation. We will discuss there's thermoanalytical data and some important reactions.