Single Crystal Growth Behavior in High-Density Nano-Si zed Aerosol Deposited Films

초록

Solid state grain growth (SSCG) is a method of growing large single crystals from seed single crystals by abnormal grain growth in a small-grained matrix. During grain growth, pores are often trapped in the matrix and remain in single crystals. Aerosol deposition (AD) is a method of manufacturing films with almost full density from nano grains by causing high energy collision between substrates and ceramic powders. AD and SSCG are used to grow single crystals with few pores. BaTiO3 films are coated on (100) SrTiO3 seeds by AD. To generate grain growth, BaTiO3 films are heated to 1,300 degrees C and held for 10 h, and entire films are grown as single crystals. The condition of grain growth driving force is Delta G(max) < Delta G(c) <= Delta G(seed). On the other hand, the condition of grain growth driving force in BaTiO3 AD films heat-treated at 1,100 and 1,200 degrees C is Delta G(c) < Delta G(max), and single crystals are not grown.

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