Thermophysical properties of 2-amino-2-methylpropan-1-ol + alkanol mixtures: Investigation of molecular interactions by insight of FT-IR spectroscopy

초록

We report the experimental data of dynamic viscosity (eta) and ultrasonic speed (u) for 2-amino-2-methylpropan-1ol (AMP) (1) + alkanol (C1-C3) (2) at T = (298.15-318.15) K and 0.1 MPa pressure. The derived excess (or deviation in) properties like dynamic viscosity (Delta eta), speed of sound (Delta u) and excess isentropic compressibility (kappa ES) were regressed through Redlich-Kister polynomial equation. The Delta eta values were analyzed in terms of an Abinitio approach, to study the intermolecular interactions between the binary components. Our analysis indicated that compared to propanol, methanol and ethanol interact strongly with AMP and 2-propanol exhibited the weakest interactions with AMP owing to steric hindrance by branched propyl group. In addition, viscosity (eta) values and ultrasonic speed (u) data were analyzed using the various thermodynamic models/correlations that agreed well with our experimental data. Furthermore, we analyzed the FT-IR spectra of pure components and their binaries and observed prevailing hydrogen bonding interactions between the N-atom and OH-group of AMP with the OH-group of alkanol. Our findings highlight the great bonding capability of AMP with lower alkanol due to its small size and linear shape and can provide information on designing effective binary mixtures (blended) solvents based on AMP for CO2 absorption.

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