Expedited access to novel hypoxia-inducible factor 1α (HIF-1α) inhibitory benzyl aryl ketones via a decarboxylative Claisen condensation or tandem decarboxylative Claisen condensation-alkylation

  • Lee, Seungbeom
  • Heo, Mi Jeong
  • Kim, Eunseo
  • Lee, Jung Min
  • Kim, Sang Geon
  • 외 3명
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초록

A series of benzyl aryl ketones, which are potentially important HIF-1 alpha inhibitors, were efficiently prepared by the decarboxylative Claisen condensation reaction. The reaction required no redox process for the ketone moiety, resulting in a one step sequence. This procedure also effectively provided a key alpha-alkylbenzyl aryl ketone intermediate by tandem decarboxylative Claisen condensation-alkylation.

키워드

BIOLOGICAL EVALUATIONIDENTIFICATIONEXPRESSIONSH-1242ANALOGSDESIGN
제목
Expedited access to novel hypoxia-inducible factor 1α (HIF-1α) inhibitory benzyl aryl ketones via a decarboxylative Claisen condensation or tandem decarboxylative Claisen condensation-alkylation
저자
Lee, SeungbeomHeo, Mi JeongKim, EunseoLee, Jung MinKim, Sang GeonKim, IljinSuh, Young-GerAn, Hongchan
DOI
10.1039/d5nj00600g
발행일
2025-11
유형
Article
저널명
New Journal of Chemistry
49
45
페이지
19515 ~ 19522