영문제목High Level Ab Initio Studies on the Gas-Phase Reactions of Vinyl Halides Activated by pi-Accepting Substituents with Halide Anions

초록

The gas-phase bimolecular reactions of 1-(R)-1-haloethenes with halide anions have been investigated theoretically at the G2M(RCC1) level of theory. For reactions of 1-(R)-1-haloethenes with R=HCC substituent, the SN2' (syn) paths are the most favorable among the possible reaction paths.