기체 브롬 원자와 실리콘 표면에 흡착된 수소 원자가의 반응

초록

The probabilty of HBr formation from the reaction of gaseous Br and adsorbed H on a Si surface has been calculated. At 1500K(gas) and 300K(surface) the reaction probabilty is about 0.2. Raising the initial vibrational state of the adsorbate(H)-surface(Si) bond from v=0 to 1,2 and 3 causes the vibrational, translational and rotational energies of the product HBr to increase equally.