Recent Advances in MnOx/CeO2-Based Ternary Composites for Selective Catalytic Reduction of NOx by NH3: A Review

초록

Recently, manganese oxides (MnOx)/cerium(IV) oxide (CeO2) composites have attracted widespread attention for the selective catalytic reduction (SCR) of nitrogen oxides (NOx) with ammonia (NH3), which exhibit outstanding catalytic performance owing to unique features, such as a large oxygen storage capacity, excellent low-temperature activity, and strong mechanical strength. The intimate contact between the components can effectively accelerate the charge transfer to enhance the electron-hole separation efficiency. Nevertheless, MnOx/CeO2 still reveals some deficiencies in the practical application process because of poor thermal stability, and a low reduction efficiency. Constructing MnOx/CeO2 with other semiconductors is the most effective strategy to further improve catalytic performance. In this article, we discuss progress in the field of MnOx/CeO2-based ternary composites with an emphasis on the SCR of NOx by NH3. Recent progress in their fabrication and application, including suitable examples from the relevant literature, are analyzed and summarized. In addition, the interaction mechanisms between MnOx/CeO2 catalysts and NOx pollutants are comprehensively dissected. Finally, the review provides basic insights into prospects and challenges for the advancement of MnOx/CeO2-based ternary catalysts.

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