새로운 광학활성을 갖는 Co(III) 복합촉매의 ECH에 대한 HKR 반응의 촉매활성과 고정화반응에 대한 연구

초록

The syntheses of optically pure chemicals have gained significant potential over recent years. We synthesize chiral Co(III) salen complexes bearing on BCl3. And this Co(III) Salen complexes are immobilized on the functionalized silica gel. This catalysts are very reactive and enantioselective in the hydrolytic kinetic resolution of racemic ECH(epichlorohydrine) with water.