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초록
A new heterogeneous system for catalytic trimethylsilylcyanation of benzaldehyde has been developed by immobilizing Ti(IV) salen onto ordered mesoporous silica(MCM-41). The heterogenized salen catalysts showed a high enantioselectivity for the addition of trimethylsilyl cyanide to benzaldehyde.
- 제목
- Enantioselectivities of Chiral Ti(IV) Salen Complexes Immobilized on MCM-41 in Asymmetric Trimethylsilylcyanation of Benzaldehyde
- 저자
- KIM GEON JOONG
- 학회명
- Preoceedings of The 2nd Joint Symposium supported by The Japan-Korea Basic Scientific Cooperation Program Title : Studies on Catalytic Materials towards Green Chemical Processes