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Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography
- Ki, Hosung;
- Kim, Tae Wu;
- Moon, Jiwon;
- Kim, Jungmin;
- Lee, Yunbeom;
- ... Kim, Jeongho;
- 외 8명
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WEB OF SCIENCE
5Citations
SCOPUS
5초록
The photoactivation mechanism of Os-3(CO)(12) at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os-3(CO)(11) with a ligand vacancy at the axial position.
키워드
SOLUTION SCATTERING REVEALS; M-3(CO)(12) M; OS3(CO)12; CLUSTERS; DYNAMICS; PHOTOCHEMISTRY; PHOTOREACTIONS; RU-3(CO)(12); REACTIVITY; PHOTOLYSIS
- 제목
- Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography
- 저자
- Ki, Hosung; Kim, Tae Wu; Moon, Jiwon; Kim, Jungmin; Lee, Yunbeom; Heo, Jun; Kim, Kyung Hwan; Kong, Qingyu; Khakhulin, Dmitry; Newby, Gemma; Kim, Joonghan; Kim, Jeongho; Wulff, Michael; Ihee, Hyotcherl
- 발행일
- 2022-06-30
- 유형
- Article
- 권
- 58
- 호
- 53
- 페이지
- 7380 ~ 7383