Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Ki, Hosung; Kim, Tae Wu; Moon, Jiwon; Kim, Jungmin; Lee, Yunbeom; Heo, Jun; Kim, Kyung Hwan; Kong, Qingyu; Khakhulin, Dmitry; Newby, Gemma; Kim, Joonghan; Kim, Jeongho; Wulff, Michael; Ihee, Hyotcherl

doi:10.1039/d2cc02438a

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Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Ki, Hosung;
Kim, Tae Wu;
Moon, Jiwon;
Kim, Jungmin;
Lee, Yunbeom;
... Kim, Jeongho;
외 8명

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초록

The photoactivation mechanism of Os-3(CO)(12) at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os-3(CO)(11) with a ligand vacancy at the axial position.

키워드

SOLUTION SCATTERING REVEALS; M-3(CO)(12) M; OS3(CO)12; CLUSTERS; DYNAMICS; PHOTOCHEMISTRY; PHOTOREACTIONS; RU-3(CO)(12); REACTIVITY; PHOTOLYSIS

제목: Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

저자: Ki, Hosung; Kim, Tae Wu; Moon, Jiwon; Kim, Jungmin; Lee, Yunbeom; Heo, Jun; Kim, Kyung Hwan; Kong, Qingyu; Khakhulin, Dmitry; Newby, Gemma; Kim, Joonghan; Kim, Jeongho; Wulff, Michael; Ihee, Hyotcherl

DOI: 10.1039/d2cc02438a

발행일: 2022-06-30

유형: Article

저널명: Chemical Communications

권: 58

호: 53

페이지: 7380 ~ 7383

언어: ENG

출판사: Royal Society of Chemistry

발행국가: 영국

분량: 4 페이지

ISSN: E 1364-548X
P 1359-7345