Understanding solid electrolyte interface formation on graphite and silicon anodes in lithium-ion batteries: Exploring the role of fluoroethylene carbonate

  • Lee, Jinhee
  • Jeong, Ji-Yoon
  • Ha, Jaeyun
  • Kim, Yong-Tae
  • Choi, Jinsub
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초록

This study explores how fluoroethylene carbonate (FEC) influences the solid electrolyte interface (SEI) layer formation during battery cycling process. FEC improves SEI properties, producing a uniform, chemically stable layer enriched with lithium fluoride. This enhances mechanical resilience and electrochemical stability. FEC also suppresses electrolyte deformation and decomposition, maintaining its initial state. The findings highlight the significance and comprehension of electrolyte additives, offering an electrolyte research pathway for improving Li-ion battery performance and durability.

키워드

Solid electrolyte interface layerElectrolyte decompositionFluoroethylene carbonateDicarboxylateLithium-ion batteryINTERPHASEMECHANISM
제목
Understanding solid electrolyte interface formation on graphite and silicon anodes in lithium-ion batteries: Exploring the role of fluoroethylene carbonate
저자
Lee, JinheeJeong, Ji-YoonHa, JaeyunKim, Yong-TaeChoi, Jinsub
DOI
10.1016/j.elecom.2024.107708
발행일
2024-06
유형
Article
저널명
Electrochemistry Communications
163