Promotional Effect of CO2 in Alkylaromatics Oxidation with MC-Type Catalytic System

초록

Cobalt peoxocarbonate could be generated from O2/CO2 in the modified MC-catalysts (Co/Mn/Br) with third metallic components such as Fe and Ni or tertiary bromides. The reaction with CO2 takes place in more milder conditions and the initial stages of reactions are more greatly affected with CO2 and oxygen consumptions also are also increased when CO2 is added in the oxidation of DMN(2,6-dimethylnaphtalene).