Synthesis of Molecularly-Imprinted Polymeric Resins via a Surfactant-Based Reverse Micellar

초록

Molecularly imprinted polymeric resins were synthesized with various reverse micellar templates. Ionic surfactants or non-ionic, amphiphilic block copolymers were used as a structure-directing agent and the polymerization of reaction media was carried out by using ultraviolet (UV) irradiation at room temperature. To explore the effect of water on the formation of a nanoscopic ordering of the supramolecuar self-assembly of amphiphiles in hydrophobic reaction media or crosslinked polymeric resins, we use small angle Xray (SAXS) and neutron (SANS) scattering, transmission electron microscopy (TEM), scanning electron microscope (SEM), Brunauer-Emmett-Teller (BET). Morphological transitions of the nanostructure were also investigated.