Nanoscale synthesis of nickel oxide@carboxy methyl cellulose@nitrogen doped carbon nanotubes supported metal organic frameworks ternary composite for use symmetric supercapacitor

  • Ramesh, Sivalingam; 
  • Rabani, Iqra; 
  • Thangavelu, Indumathi; 
  • Yadav, H. M.; 
  • Selvaraj, Manickam; 
  • ... Kim, Joo-Hyung; 
  • 외 3명
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초록

Metal-organic frameworks (MOFs) are a novel class of porous materials that combine organic linkers and inorganic metal ions. Supercapacitors use a large specific surface area, adjustable architecture, and tunable porosity and pore diameters to improve the electrochemical performances with metal sulfides. The main goal of this study was to make a nickel oxide ternary composite using a hydrothermal method with urea as a catalyst for electrochemical uses. We characterized these fabricated composite materials using analytical and morphological characterization for their confirmation. These results show that the composite electrode had a great specific capacitance of 464 F/g at 0.5 A/g in a 1 M KOH electrolyte when set up with three electrodes. The symmetric two-electrode system showed 52.83 F/g at 0.5 A/g with an excellent energy density of 13.14 Whkg-1 and a power density of 616 Wkg-1 via 1 M KOH electrolyte. The fabricated ternary composite electrode demonstrated cyclic stability, with an excellent retention rate of 89 % after 7000 cycles. Therefore, the fabricated ternary composite electrode materials have enormous potential for electrochemical storage properties.

키워드

Nickel oxide (NiO); Carboxymethyl cellulose (CMC); N-MWCNT; MOF-67; Ternary composite; Electrochemical supercapacitor; ELECTRODE MATERIALS; HIGH CAPACITANCE; FACILE SYNTHESIS; PERFORMANCE; NIO; ENERGY; NANOCOMPOSITE; NANOPARTICLES; NETWORKS; STORAGE
제목
Nanoscale synthesis of nickel oxide@carboxy methyl cellulose@nitrogen doped carbon nanotubes supported metal organic frameworks ternary composite for use symmetric supercapacitor
저자
Ramesh, Sivalingam; Rabani, Iqra; Thangavelu, Indumathi; Yadav, H. M.; Selvaraj, Manickam; Saritha, Appukuttan; Seo, Young-Soo; Kim, Joo-Hyung; Kim, Heung Soo
DOI
10.1016/j.ijbiomac.2025.144901
발행일
2025-07
유형
Article
저널명
International Journal of Biological Macromolecules
권
318