Kinetics and Mechanism of the Thiophosphoryl Transfer Reactions from Aryl Phenyl Chlorothiophosphates towards Anilines and Pyridines in Acetonitrile

초록

Kinetic studies on the thiophophoryl transfer reactions from aryl phenyl chlorothiophosphates with anilines and pyridines are investigated in acetonitrile at 55 degree and 35 degree, respectively. Rates are much faster with pyridines than anilines as the basicity is increased.