높게 들뜬 톨루엔과 염화수소간의 충돌에 의한 분자내 에너지 이동 및 결합해리

초록

The collision-induced intramolecular energy flow and CH bond dissociation have been studied by classical dynamical procedures. At 300K, the energy loss by the excited molecule upon collision is not large and it increases gradually with increasing total vibrational energy content between 20000 and 45000 cm-1. Above 45000cm-1, energy loss decreases slowly.