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초록
The thermal isomerizations of ketenimines to nitriles involve a "homolytic" transition state (TS) as the major contributor to the structure of the TS. The rates have been fitted to Hammett dual correlations. The magnitudes of ρ·/ρ represent the relative weights in the TS assuming homolytic character.
- 제목
- Homolytic Rearrangements of Ketenimines to Nitriles : Employments of Hammett Dual Parameters
- 제목 (타언어)
- 키틴이민의 니트릴로의 균형분해 자리옮김 반응 : 하메트 듀얼 관계식 사용
- 저자
- Sung Soo Kim
- 학회명
- J. Org. Chem.